Phase 1: Prep Work and Marination. In a blender or food processor, combine the adobo sauce, chopped chipotle peppers, olive oil, orange juice, lime juice, cumin, oregano, smoked paprika, garlic powder, and a generous pinch of kosher salt. Blend until smooth.
Place the chicken thighs in a large bowl and pour the marinade over them. Massage the liquid into the meat, ensuring every piece is coated. Let marinate for at least 30 minutes at room temperature.
Phase 2: Cooking the Base. Wash your rice in a fine-mesh strainer until the water runs clear. Heat 1 tablespoon of oil in a saucepan, add the rinsed rice, and toast for 2 minutes. Add water and salt, bring to a boil, cover, and drop the heat to the lowest setting for 15 minutes.
Empty the rinsed black beans into a small pot. Add a splash of water, a dash of cumin, and a pinch of salt. Simmer gently on low heat.
Phase 3: Searing and Finishing Touches. Heat a large cast-iron skillet over medium-high heat until smoking hot. Add a drizzle of high-heat oil. Sear the chicken thighs for 5-6 minutes per side until a dark crust forms and the internal temperature reaches 165°F.
Remove the chicken to a cutting board and let it rest for 5 minutes before chopping.
Fluff the cooked rice with a fork and fold in fresh lime juice and chopped cilantro.
Assemble: Layer the cilantro-lime rice at the bottom of a wide bowl. Top with warm black beans, chopped smoky chicken, fresh pico de gallo, shredded cheese, sour cream, and guacamole. Serve immediately.